First-Row Transition Metals in Binuclear Cyclopentadienylmetal Derivatives of Tetramethyleneethane: η3,η3 versus η4,η4 Ligand–Metal Bonding Related to Spin State and Metal

First-Row Transition Metals in Binuclear Cyclopentadienylmetal Derivatives of Tetramethyleneethane: η3,η3 versus η4,η4 Ligand–Metal Bonding Related to Spin State and Metal–Metal Bonds

Published:2014-06-26 Issue:13 Volume:33 Page:3489-3499
ISSN:0276-7333
Container-title:Organometallics
language:en
Short-container-title:Organometallics

Author:

Li Huidong¹,Feng Hao¹,Sun Weiguo¹²,Fan Qunchao¹,King R. Bruce³,Schaefer Henry F.³

Affiliation:

1. School of Physics and Chemistry, Research Center for Advanced Computation, Xihua University, Chengdu, Sichuan 610039, People’s Republic of China

2. Institute of Atomic and Molecular Physics, Sichuan University, Chengdu, Sichuan 610065, People’s Republic of China

3. Department of Chemistry and Center for Computational Chemistry University of Georgia, Athens, Georgia 30602, United States

Funder

National Natural Science Foundation of China

National Science Foundation

Publisher

American Chemical Society (ACS)

Subject

Inorganic Chemistry,Organic Chemistry,Physical and Theoretical Chemistry

Link

https://pubs.acs.org/doi/pdf/10.1021/om5004072

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5. Reactions of compounds containing nickel-nickel, nickel-molybdenum, and nickel-tungsten bonds with allene and 1,1-dimethylallene. X-ray diffraction studies of the .pi.-allylic complexes NiMo(.mu.-CO)(CO){.mu.-.eta.3,.eta.3-C9H12}(.eta.5-C5H5)(.eta.5-C5H4Me) and NiMo(.mu.-CO)(CO){.mu.-.eta.1,.eta.3-C(Me)C(Me)CH2}(.eta.5-C5H5)(.eta.5-C5H4Me) (Ni-Mo)

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