Coordination Chemistry and Reactivity of Monomeric Alkoxides and Amides of Magnesium and Zinc Supported by the Diiminato Ligand CH(CMeNC6H3-2,6-iPr2)2. A Comparative Study

Author:

Chisholm Malcolm H.1,Gallucci Judith1,Phomphrai Khamphee1

Affiliation:

1. Department of Chemistry, Newman & Wolfrom Laboratories, The Ohio State University, 100 W. 18th Avenue, Columbus, Ohio 43210-1185

Publisher

American Chemical Society (ACS)

Subject

Inorganic Chemistry,Physical and Theoretical Chemistry

Reference20 articles.

1. Cotton, F. A.; Wilkinson, E.; Murillo, C. A.; Bochmann, M.AdvancedInorganic Chemistry, 6th ed.; John Wiley & Sons:  New York, 1999; pp 1302−1304.

2. Campbell, N. A.Biology, 3rd ed.; Benjamin/Cummings Publishing Co.  California, 1993; pp 718−722, 811−814.

3. Huheey, J. E.; Keiter, E. A.; Keiter, R. L.Inorganic Chemistry: iPrnciples of Structure and Reactivity, 4th ed.; Harper Collins College Publishers:  New York, 1993; pp 344−348.

4. Molecular Design of Single-Site Metal Alkoxide Catalyst Precursors for Ring-Opening Polymerization Reactions Leading to Polyoxygenates. 1. Polylactide Formation by Achiral and Chiral Magnesium and Zinc Alkoxides, (η3-L)MOR, Where L = Trispyrazolyl- and Trisindazolylborate Ligands

5. Polymerization of Lactide with Zinc and Magnesium β-Diiminate Complexes:  Stereocontrol and Mechanism

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