1. EME/XaRMAE/IN2UB, Departament d'Electronica, Universitat de Barcelona, C/ Marti i Franques 1, Barcelona, E-08028, Spain, Nanocrystalline Materials and Thin Film Systems, Leibniz-Institute of New Materials, Saarbruecken, D-66123, Germany, and Department of Inorganic Chemistry, University of Cologne, Cologne, D-50939, Germany