A PCN Ligand System. Exclusive C−C Activation with Rhodium(I) and C−H Activation with Platinum(II)
Author:
Affiliation:
1. Departments of Organic Chemistry and Chemical Services, The Weizmann Institute of Science, Rehovot 76100, Israel
Publisher
American Chemical Society (ACS)
Subject
Inorganic Chemistry,Organic Chemistry,Physical and Theoretical Chemistry
Link
https://pubs.acs.org/doi/pdf/10.1021/om9703200
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1. Tuning the reactivity of metals held in a rigid ligand environment
2. New Homogeneous Catalysts in the Addition of Polyhalogenoalkanes to Olefins; Organonickel(II) Complexes [Ni{C6H3(CH2NMe2)2-o,o'}X] (X = Cl, Br, I)
3. Oxidation of organoplatinum(II) halides with halogens or copper(II) halides. Syntheses and the molecular structure of [Pt(IV)Cl3{C6H3(CH2NMe2)2-o,o'}]
4. Model for the initial stage in the oxidative addition of I2 to organoplatinum(II) compounds. X-ray structure of square-pyramidal [PtIII{C6H3(CH2NMe2)2-o,o'}(.eta.1-I2)] containing a linear Pt-I-I arrangement
5. 1,2-Methyl shift between platinum and the coordinated aryl group in the reaction of methyl iodide with 2,6-bis[(dimethylamino)methyl]phenyl-N,N',C complexes of platinum(II). X-ray crystal structure of the arenonium-platinum compound [Pt(o-tolyl)(MeC6H3(CH2NMe2)2-o,o')]I
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