Chiral Organolithium Complexes: The Structure of β-Lithiated β-Phenylcarboxamides and the Mechanism of Asymmetric Substitution in the Presence of (−)-Sparteine-Reference-Cited by-同舟云学术

Chiral Organolithium Complexes: The Structure of β-Lithiated β-Phenylcarboxamides and the Mechanism of Asymmetric Substitution in the Presence of (−)-Sparteine

Published:1996-01-01 Issue:46 Volume:118 Page:11391-11398
ISSN:0002-7863
Container-title:Journal of the American Chemical Society
language:en
Short-container-title:J. Am. Chem. Soc.

Author:

Gallagher Donald J.¹,Du Hua¹,Long Scott A.¹,Beak Peter¹

Affiliation:

1. Contribution from the Roger Adams Laboratory, Department of Chemistry, University of Illinois at Urbana-Champaign, Urbana, Illinois 61801

Publisher

American Chemical Society (ACS)

Subject

Colloid and Surface Chemistry,Biochemistry,General Chemistry,Catalysis

Link

https://pubs.acs.org/doi/pdf/10.1021/ja962430o

Reference22 articles.

1. Enantioselective synthesis via sparteine-induced asymmetric deprotonation

2. (−)-Sparteine-Mediated α-Lithiation of N-Boc-N-(p-methoxyphenyl)benzylamine: Enantioselective Syntheses of (S) and (R) Mono- and Disubstituted N-Boc-benzylamines

3. Enantioselective Deprotonation as a Vehicle for the Asymmetric Synthesis of C2-Symmetric P-Chiral Diphosphines

4. Direct and Highly Enantioselective Synthesis of Ferrocenes with Planar Chirality by (−)-Sparteine-Mediated Lithiation

5. Asymmetric substitution: highly enantioselective substitutions induced at the carbanion of a racemic organolithium substrate by (-)-sparteine

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