Theoretical Analysis of the Methane Elimination from Oxonium Cations [R3O]+, R = H, CH3
Author:
Affiliation:
1. Department of Chemistry, University of Leuven, Celestijnenlaan 200F, 3001 Leuven, Belgium, and Département de Chimie, Laboratoire des Mécanismes Réactionnels CNRS/URA 1307, Ecole Polytechnique, 91128 Palaiseau Cedex, France
Publisher
American Chemical Society (ACS)
Subject
Physical and Theoretical Chemistry,General Engineering
Link
https://pubs.acs.org/doi/pdf/10.1021/jp952453%2B
Reference19 articles.
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2. Gaseous [H2, C, N]+ and [H3, C, N]+.cntdot. ions. Generation, heat of formation, and dissociation characteristics of methylenenitrenium(1+) ([H2CN]+), iminomethylene(1+) ([HCNH]+), aminomethylidene(1+) ([CNH2]+), formaldimine(1+.cntdot.) ([H2CNH]+.cntdot.), and aminomethylene(1+.cntdot.) ([HCNH2]+.cntdot.) ions
3. Fragmentation of the trimethyloxonium cation and of protonated dimethylether studied in a tandem quadrupole mass spectrometer at medium pressure
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