Silver(I)-Catalyzed Insertion of Carbene into Alkane C–H Bonds and the Origin of the Special Challenge of Methane Activation Using DFT as a Mechanistic Probe-Reference-Cited by-同舟云学术

Silver(I)-Catalyzed Insertion of Carbene into Alkane C–H Bonds and the Origin of the Special Challenge of Methane Activation Using DFT as a Mechanistic Probe

Published:2012-08-31 Issue:10 Volume:2 Page:2066-2078
ISSN:2155-5435
Container-title:ACS Catalysis
language:en
Short-container-title:ACS Catal.

Author:

Flores Jaime A.¹,Komine Nobuyuki¹,Pal Kuntal¹,Pinter Balazs¹,Pink Maren¹,Chen Chun-Hsing¹,Caulton Kenneth G.¹,Mindiola Daniel J.¹

Affiliation:

1. Department of Chemistry and Molecular Structure Center, Indiana University, Bloomington, Indiana 47405, United States

Publisher

American Chemical Society (ACS)

Subject

Catalysis,General Chemistry

Link

https://pubs.acs.org/doi/pdf/10.1021/cs300256b

Reference90 articles.

1. Transition-metal-catalysed reactions of diazoesters. Insertion into C–H bonds of paraffins by carbenoids

2. New Catalysts and Conditions for a CH Insertion Reaction Identified by High Throughput Catalyst Screening

3. Silver(I) Scorpionate Mediated Insertion of Carbenes into Aliphatic C−H Bonds

4. Intermolecular carbon-hydrogen insertion of copper carbenoids

5. Catalytic asymmetric CH activation of sp3 hybridized CH bonds by means of carbenoid CH insertions: applications in organic synthesis

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