Planar Homotropenylium Cation: A Transition State with Reversed Aromaticity

Author:

Gibson Christopher M.1,Havenith Remco W. A.23,Fowler Patrick W.1,Jenneskens Leonardus W.4

Affiliation:

1. Department of Chemistry, University of Sheffield, Sheffield, S3 7HF, U.K.

2. Theoretical Chemistry, Zernike Institute for Advanced Materials and Stratingh Institute for Chemistry, Rijksuniversiteit, Groningen, Nijenborgh 4, 9747 AG Groningen, The Netherlands

3. Ghent Quantum Chemistry Group, Department of Inorganic and Physical Chemistry, Ghent University, Krijgslaan 281 (S3), B-9000 Ghent, Belgium

4. Organic Chemistry and Catalysis, Debye Institute for Nanomaterials Science, Utrecht University, Universiteitsweg 99, 3584 CG Utrecht, The Netherlands

Publisher

American Chemical Society (ACS)

Subject

Organic Chemistry

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1. Aromaticity Reversal Induced by Vibrations in Cyclo[16]carbon;Journal of the American Chemical Society;2023-12-01

2. Gas-Phase Formation of 1,3,5,7-Cyclooctatetraene (C8H8) through Ring Expansion via the Aromatic 1,3,5-Cyclooctatrien-7-yl Radical (C8H9) Transient;Journal of the American Chemical Society;2022-12-01

3. Ab initio calculations of ring current density of some benzenoids;2ND INTERNATIONAL CONFERENCE ON MATERIALS ENGINEERING & SCIENCE (IConMEAS 2019);2020

4. Hückel and Möbius Aromaticity in Charged Sigma Complexes;Chemistry – A European Journal;2019-05-09

5. Carbocations;Organic Reaction Mechanisms Series;2019-03-07

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