Room Temperature Au(I)-Catalyzed exo-Selective Cycloisomerization of Acetylenic Acids:  An Entry to Functionalized γ-Lactones

Author:

Genin Emilie1,Toullec Patrick Yves1,Antoniotti Sylvain1,Brancour Célia1,Genêt Jean-Pierre1,Michelet Véronique1

Affiliation:

1. Laboratoire de Synthèse Sélective Organique et Produits Naturels, E.N.S.C.P., UMR 7573, 11 rue P. et M. Curie, F-75231 Paris Cedex 05, France

Publisher

American Chemical Society (ACS)

Subject

Colloid and Surface Chemistry,Biochemistry,General Chemistry,Catalysis

Reference41 articles.

1. For representative reviews, see:  (a) Hashmi, A. S. K.Angew.Chem.Int. Ed.2005,44, 6990−6993. (b) Höffmann-Röder, A.; Krause, N.Org. Biomol.Chem.2005,3, 387−391. (c) Hashmi, A. S. K.Gold Bull.2004,37, 51−65. (d) Arcadi, A.; Di Giuseppe, S.Curr. Org. Chem.2004,8, 795−812. (e) Bianchi, G.; Arcadi, A. InTargets in Heterocyclic Systems; Attanasi, O. A., Spinelli, D., Eds.; Springer:  Berlin, 2004; Vol. 8, pp 82−119. (f) Hashmi, A. S. K.Gold Bull.2003,36, 3−9. (g) Dyker, G.Angew.Chem.Int. Ed.2000,39, 4237−4239.

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3. Unusual Gold(I)-Catalyzed Isomerization of 3-Hydroxylated 1,5-Enynes: Highly Substrate-Dependent Reaction Manifolds

4. Intramolecular [4 + 2] Cycloadditions of 1,3-Enynes or Arylalkynes with Alkenes with Highly Reactive Cationic Phosphine Au(I) Complexes

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