[5,10,15,20-Tetrakis(4-((pentaammineruthenio)- cyano)phenyl)porphyrinato]cobalt(II) Immobilized on Graphite Electrodes Catalyzes the Electroreduction of O2 to H2O, but the Corresponding 4-Cyano-2,6-dimethylphenyl Derivative Catalyzes the Reduction Only to H2O2
Author:
Affiliation:
1. Arthur Amos Noyes Laboratories, Division of Chemistry and Chemical Engineering, California Institute of Technology, Pasadena, California 91125
Publisher
American Chemical Society (ACS)
Subject
Inorganic Chemistry,Physical and Theoretical Chemistry
Link
https://pubs.acs.org/doi/pdf/10.1021/ic970275o
Reference18 articles.
1. Multiple intramolecular electron transfer in the catalysis of the reduction of dioxygen by cobalt meso-tetrakis(4-pyridyl)porphyrin to which four Ru(NH3)5 groups are coordinated
2. Electrocatalysis of the reduction of molecular oxygen to water by tetraruthenated cobalt meso-tetrakis(4-pyridyl)porphyrin adsorbed on graphite electrodes
3. Electrocatalysis of the reduction of dioxygen by adsorbed cobalt 5,10,15,20-tetraarylporphyrins to which one, two, or three pentaammineruthenium(2+) centers are coordinated
4. Electrocatalysts for the four-electron reduction of dioxygen based on adsorbed cobalt tetrapyridylporphyrin molecules linked by aquaammine complexes of ruthenium(II)
5. New Electrocatalysts for the Four-Electron Reduction of Dioxygen Based on (5,10,15-Tris(pentaammineruthenium(II)-4-cyanophenyl)-20- (1-methylpyridinium-4-yl)porphyrinato)cobalt(II) Immobilized on Graphite Electrodes
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