Two-Coordinate, Nonlinear Vanadium(II) and Chromium(II) Complexes of the Silylamide Ligand–N(SiMePh2)2: Characterization and Confirmation of Orbitally Quenched Magnetic Moments in Complexes with Sub-d5 Electron Configurations-Reference-Cited by-同舟云学术

Two-Coordinate, Nonlinear Vanadium(II) and Chromium(II) Complexes of the Silylamide Ligand–N(SiMePh2)2: Characterization and Confirmation of Orbitally Quenched Magnetic Moments in Complexes with Sub-d5 Electron Configurations

Published:2021-02-23 Issue:6 Volume:60 Page:4108-4115
ISSN:0020-1669
Container-title:Inorganic Chemistry
language:en
Short-container-title:Inorg. Chem.

Author:

Freitag Kerstin¹,Stennett Cary R.²^ORCID,Mansikkamäki Akseli³^ORCID,Fischer Roland A.¹^ORCID,Power Philip P.²^ORCID

Affiliation:

1. Inorganic and Metalorganic Chemistry, Technical University Munich, D-85748, Garching, Germany

2. Department of Chemistry, University of California, Davis, One Shields Avenue, Davis, California 95616, United States

3. NMR Research Unit, Faculty of Science, University of Oulu, P.O. Box 3000, Oulu, FIN-90014, Finland

Funder

Division of Chemistry

Oulun Yliopisto

Suomen Akatemia

Verband der Chemischen Industrie

Research School, Ruhr University Bochum

Publisher

American Chemical Society (ACS)

Subject

Inorganic Chemistry,Physical and Theoretical Chemistry

Link

https://pubs.acs.org/doi/pdf/10.1021/acs.inorgchem.1c00168

Reference60 articles.

1. Silylamido-Derivate von Eisen und Kobalt

2. Silylamido-Verbindungen von Chrom, Mangan, Nickel und Kupfer

3. The crystal molecular structure of ?bis(hexamethyldisilylamido) manganese?

4. Three-coordinate metal amides of manganese(II) and cobalt(II): synthesis and x-ray structure of the first tris(silylamide) of manganese and the x-ray crystal structures of [M2(N(SiMe3)2)4] (M = Mn, Co)

5. Three-coordinate iron complexes: x-ray structural characterization of the iron amide-bridged dimers [Fe(NR2)2]2 (R = SiMe3, C6H5) and the adduct Fe[N(SiMe3)2]2(THF) and determination of the association energy of the monomer Fe{N(SiMe3)2}2 in solution

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