Spectroscopic X-ray and Mössbauer Characterization of M6 and M5 Iron(Molybdenum)-Carbonyl Carbide Clusters: High Carbide-Iron Covalency Enhances Local Iron Site Electron Density Despite Cluster Oxidation
Author:
Affiliation:
1. Department of Inorganic Spectroscopy, Max Planck Institute for Chemical Energy Conversion, Stiftstrasse 34-36, D-45470, Mülheim an der Ruhr, Germany
2. Department of Chemistry, The University of Texas at Austin, Austin, Texas 78712, United States
Funder
Welch Foundation
Research Corporation for Science Advancement
Deutsche Forschungsgemeinschaft
Max-Planck-Gesellschaft
Alexander von Humboldt-Stiftung
FP7 Ideas: European Research Council
National Science Foundation
Fulbright Research Award
Publisher
American Chemical Society (ACS)
Subject
Inorganic Chemistry,Physical and Theoretical Chemistry
Link
http://pubs.acs.org/doi/pdf/10.1021/acs.inorgchem.9b01870
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1. The Preparation, Properties and Structure of the Iron Carbonyl Carbide Fe5(CO)15C
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5. Synthesis and Structure of Tetrairidium Clusters on TiO2 Powder: Characterization by Infrared and Extended X-ray Absorption Fine Structure Spectroscopies
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