Separating Innocence and Non-Innocence of Ligands and Metals in Complexes [(L)Ru(acac)2]n (n = −1, 0, +1; L = o-Iminoquinone or o-Iminothioquinone)
Author:
Affiliation:
1. Department of Chemistry, Indian Institute of Technology-Bombay, Powai, Mumbai 400076, India, and Institut für Anorganische Chemie, Universität Stuttgart, Pfaffenwaldring 55, D-70550 Stuttgart, Germany
Publisher
American Chemical Society (ACS)
Subject
Inorganic Chemistry,Physical and Theoretical Chemistry
Link
https://pubs.acs.org/doi/pdf/10.1021/ic034469h
Reference41 articles.
1. “Non-innocent” ligands can occur in at least two readily accessible oxidation states which may introduce ambiguity in oxidation state assignment unless the “correct” oxidation numbers for metal and ligand can be proven experimentally. (a) Jørgensen, C. K.Oxidation Numbers andOxidation States; Springer: Berlin, 1969; p 291. (b) Ward, M. D.; McCleverty, J. A.J. Chem. Soc., Dalton Trans.2002, 275.
2. Induced electron transfer in ammineruthenium catechol and quinone complexes
3. Catechol-quinone redox series involving bis(bipyridine)ruthenium(II) and tetrakis(pyridine)ruthenium(II)
4. Ruthenium(II) coordination to a model for the topasemiquinone cofactor of amine oxidases. Resolution of1H and99,101Ru EPR hyperfine structure
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