Stereomutation of Conformational Enantiomers of 9-Isopropyl-9-formylfluorene and Related Acyl Derivatives
Author:
Affiliation:
1. Department of Chemistry, University of Basilicata, via N. Sauro 85, Potenza 85100, Italy, and Department of Organic Chemistry “A. Mangini”, University of Bologna, Viale Risorgimento 4, Bologna 40136, Italy
Publisher
American Chemical Society (ACS)
Subject
Organic Chemistry
Link
https://pubs.acs.org/doi/pdf/10.1021/jo8008897
Reference31 articles.
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2. Rotational isomerism in fluorene derivatives. XX. Conformational equilibria of 9-substituted 9-(o-methylthiomethylphenyl)- and 9-substituted 9-(o-methylsulfinylmethylphenyl)fluorenes
3. Correlated Rotations in Benzylfluorene Derivatives: Structure, Conformation, and Stereodynamics
4. Structure-activity relationship studies in the field of calcium(II) antagonists. Effect of modifications at the tetrasubstituted carbon of verapamil-like compounds
5. As often observed in conformational processes, the free energy of activation was found independent of temperature within the errors, indicating a negligible value of ΔS≠. See, for instance:
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2. Intramolecular Aromatic Carbenoid Insertion of Biaryldiazoacetates for the Regioselective Synthesis of Fluorenes;Chemistry - An Asian Journal;2011-05-12
3. Steric effects which determine the conformational preferences and stereodynamic processes of aryl fluorenyl ketones;Organic & Biomolecular Chemistry;2009
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