Reactivity of the Unsaturated Complex [(C6Me6)2Ru2(μ2-H)3]+ toward Phosphines: Synthesis and Molecular Structure of the Dinuclear Cations [(C6Me6)2Ru2(μ2-PR2)(μ2-H)2]+ and Characterization of the P−C Bond Activation Intermediate [(C6Me6)2Ru2(μ2-PPh2)(μ2-H)(μ2-Ph)]+
Author:
Affiliation:
1. Institut de Chimie, Université de Neuchâtel, Avenue de Bellevaux 51, CH-2007 Neuchâtel, Suisse, Laboratoire FEMTO-ST/LPMO, CNRS UMR 6174, 32 Avenue de l'Observatoire, F-25044 Besançon, France
Publisher
American Chemical Society (ACS)
Subject
Inorganic Chemistry,Organic Chemistry,Physical and Theoretical Chemistry
Link
https://pubs.acs.org/doi/pdf/10.1021/om049025n
Reference59 articles.
1. Ligand Bite Angle Effects in Metal-catalyzed C−C Bond Formation
2. (b) Tolman, C. A.; Faller, J. W. InHomogeneous Catalysis with Metal Phosphine Complexes; Pignolet, L. H., Ed.; Plenum Press: New York, 1983; pp 13−109.
3. Mechanistic Pathways in the Catalytic Carbonylation of Methanol by Rhodium and Iridium Complexes
4. Hydroformylation of alkenes by use of rhodium complex catalysts
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