Catalytic 1,3-Proton Transfer in Alkenes Enabled by Fe═NR Bond Cooperativity: A Strategy for p<i>K</i><sub>a</sub>-Dictated Regioselective Transposition of C═C Double Bonds-Reference-Cited by-同舟云学术

Catalytic 1,3-Proton Transfer in Alkenes Enabled by Fe═NR Bond Cooperativity: A Strategy for pK_a-Dictated Regioselective Transposition of C═C Double Bonds

Published:2023-05-25 Issue:22 Volume:145 Page:11978-11987
ISSN:0002-7863
Container-title:Journal of the American Chemical Society
language:en
Short-container-title:J. Am. Chem. Soc.

Author:

Gao Yafei¹^ORCID,Li Xuelian²,Stevens Jeremiah E.³^ORCID,Tang Hao²^ORCID,Smith Jeremy M.¹^ORCID

Affiliation:

1. Department of Chemistry, Indiana University, Bloomington, Indiana 47405, United States

2. College of Chemistry and Materials Engineering, Wenzhou University, Wenzhou, Zhejiang 325035, P. R. China

3. Department of Chemistry and Biochemistry, The Ohio State University, Columbus, Ohio 43210, United States

Funder

Wenzhou Municipal Science and Technology Bureau

Office of Multidisciplinary Activities

Basic Energy Sciences

Natural Science Foundation of Zhejiang Province

Publisher

American Chemical Society (ACS)

Subject

Colloid and Surface Chemistry,Biochemistry,General Chemistry,Catalysis

Link

https://pubs.acs.org/doi/pdf/10.1021/jacs.2c13350

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4. Positional and Geometrical Isomerisation of Alkenes: The Pinnacle of Atom Economy

5. In Situ Generated Bulky Palladium Hydride Complexes as Catalysts for the Efficient Isomerization of Olefins. Selective Transformation of Terminal Alkenes to 2-Alkenes

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