1. Departamento de Química, Universidade Estadual de Maringá, CEP-87020-900, Maringá, PR, Brazil, Department of Physics, FCEyN, University of Buenos Aires and CONICET, Buenos Aires, Argentina, and Department of Organic Chemistry, Chemistry Institute, P.O. Box 6154, University of Campinas, UNICAMP, CEP: 13084-971 Campinas, SP, Brazil