Electron-Withdrawing Substituents Decrease the Electrophilicity of the Carbonyl Carbon. An Investigation with the Aid of 13C NMR Chemical Shifts, ν(CO) Frequency Values, Charge Densities, and Isodesmic Reactions To Interprete Substituent Effects on Reactivity
Author:
Affiliation:
1. Department of Chemistry, University of Turku, FIN-20014 Turku, Finland, and University of Potsdam, D-14415 Potsdam, POB 691553, Germany
Publisher
American Chemical Society (ACS)
Subject
Organic Chemistry
Link
https://pubs.acs.org/doi/pdf/10.1021/jo020121c
Reference63 articles.
1. Connors, K. A.Structure Reactivity Relationships: the Study ofReaction Rates in Solution; VCH Publishers: New York, 1990; Chapter 7, p 311.
2. Correlation analysis of carbonyl carbon 13C NMR chemical shifts, IR absorption frequencies and rate coefficients of nucleophilic acyl substitutions. A novel explanation for the substituent dependence of reactivity
3. On the relative leaving group abilities of imidazole and the substituted phenoxide ions. The effect of the acyl group
4. (a) Kalinowski, H.O.; Berger, S.; Braun, S.Carbon-13 NMRSpectroscopy; Wiley: Chichester, 1988; Chapter 3, p 92.
Cited by 97 articles. 订阅此论文施引文献 订阅此论文施引文献,注册后可以免费订阅5篇论文的施引文献,订阅后可以查看论文全部施引文献
1. The α-alkylation of ketones in flow;Reaction Chemistry & Engineering;2023
2. Fluorescent carbon dots based phytosensor for indoor formaldehyde pollution monitoring;Plant Nano Biology;2022-11
3. Highly Improved Chiral-Selective Resolution in Pillar[5]arene-Functionalized Molecularly Imprinted Membranes;ACS Applied Polymer Materials;2022-08-26
4. Surface functionalization of graphene oxide with tannic acid: Covalent vs non-covalent approaches;Journal of Molecular Liquids;2022-07
5. Electrophilicity index revisited;Journal of Computational Chemistry;2022-05-12
1.学者识别学者识别
2.学术分析学术分析
3.人才评估人才评估
"同舟云学术"是以全球学者为主线,采集、加工和组织学术论文而形成的新型学术文献查询和分析系统,可以对全球学者进行文献检索和人才价值评估。用户可以通过关注某些学科领域的顶尖人物而持续追踪该领域的学科进展和研究前沿。经过近期的数据扩容,当前同舟云学术共收录了国内外主流学术期刊6万余种,收集的期刊论文及会议论文总量共计约1.5亿篇,并以每天添加12000余篇中外论文的速度递增。我们也可以为用户提供个性化、定制化的学者数据。欢迎来电咨询!咨询电话:010-8811{复制后删除}0370
www.globalauthorid.com
TOP
Copyright © 2019-2024 北京同舟云网络信息技术有限公司 京公网安备11010802033243号 京ICP备18003416号-3