A Novel, Highly Selective, and General Methodology for the Synthesis of 1,5-Diene-Containing Oligoisoprenoids of All Possible Geometrical Combinations Exemplified by an Iterative and Convergent Synthesis of Coenzyme Q10-Reference-Cited by-同舟云学术

A Novel, Highly Selective, and General Methodology for the Synthesis of 1,5-Diene-Containing Oligoisoprenoids of All Possible Geometrical Combinations Exemplified by an Iterative and Convergent Synthesis of Coenzyme Q10

Published:2002-01-01 Issue:2 Volume:4 Page:261-264
ISSN:1523-7060
Container-title:Organic Letters
language:en
Short-container-title:Org. Lett.

Author:

Negishi Ei-ichi¹,Liou Show-Yee¹,Xu Caiding¹,Huo Shouquan¹

Affiliation:

1. Herbert C. Brown Laboratories of Chemistry, Purdue University, West Lafayette, Indiana 47907-1393

Publisher

American Chemical Society (ACS)

Subject

Organic Chemistry,Physical and Theoretical Chemistry,Biochemistry

Link

https://pubs.acs.org/doi/pdf/10.1021/ol010263d

Reference28 articles.

1. A general method for the synthesis of E and/or Z oligoisoprenoids based on Pd-catalyzed homoallyl-alkenyl and homopropargyl-alkenyl cross coupling and Zr-catalyzed carboalumination

2. A versatile and selective route to difunctional trisubstituted (E)-alkene synthons via zirconium-catalyzed carboalumination of alkynes

3. Selective carbon-carbon bond formation via transition metal catalysts. 8. Controlled carbometalation. Reaction of acetylenes with organoalane-zirconocene dichloride complexes as a route to stereo- and regio-defined trisubstituted olefins

4. Anti-Carbometalation of Homopropargyl Alcohols and Their Higher Homologues via Non-Chelation-Controlled Syn-Carbometalation and Chelation-Controlled Isomerization

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