Dissociative and Nondissociative Pathways in the endo to exo Isomerization of Tetramethyl-o-xylylene Complexes of Ruthenium and Osmium, ML3{η4-o-C6Me4(CH2)2} (M = Ru, L = PMe3; M = Os, L = PMe3, PMe2Ph). Formation of Hexamethylbenzene-1,2-diyl Complexes by Ligand Addition to the exo-Osmium Complexes
Author:
Affiliation:
1. Research School of Chemistry and the Department of Chemistry, Australian National University, Canberra, ACT 0200, Australia
Publisher
American Chemical Society (ACS)
Subject
Inorganic Chemistry,Organic Chemistry,Physical and Theoretical Chemistry
Link
https://pubs.acs.org/doi/pdf/10.1021/om9804226
Reference64 articles.
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2. Organometallic electron-reservoirs. 37. Electron-transfer chemistry of the 20-electron complex [Fe0(C6Me6)2] and of the 19-electron complex [FeI(C6Me6)(.eta.5-C6Me6H)]: mild carbon-hydrogen activation by oxygen via superoxide ion and functionalization of the exocyclic methylenes in the resulting complexes [Fe0(C6Me6)(.eta.4-polyene)]
3. Transition metal stabilized o-xylylenes. Reactivity of the novel ruthenium o-xylylene complex, Ru(.eta.6-C6Me6)[.eta.4-C6Me4(CH2)2]
4. Synthesis, structure, and reactivity of Ru(.eta.6-C6Me6)[.eta.4-C6Me4(CH2)2]. An unusual transition-metal o-xylylene complex
5. O-chinodimethan - und 2. 2-dimethyl-iso-inden-eisen-tricarbonyl
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