Charge-Transfer Character Drives Möbius Antiaromaticity in the Excited Triplet State of Twisted [28]Hexaphyrin

Author:

Ema Fumitoshi1,Tanabe Mana2,Saito Shohei3ORCID,Yoneda Tomoki3ORCID,Sugisaki Kenji4ORCID,Tachikawa Takashi15ORCID,Akimoto Seiji1ORCID,Yamauchi Seigo2,Sato Kazunobu4ORCID,Osuka Atsuhiro3ORCID,Takui Takeji4ORCID,Kobori Yasuhiro15ORCID

Affiliation:

1. Department of Chemistry, Graduate School of Science, Kobe University, 1-1 Rokkodai-cho, Nada-ku, Kobe 657-8501, Japan

2. Institute of Multidisciplinary Research for Advanced Materials, Tohoku University, Katahira 2-1-1, Aoba-ku, Sendai 980-8577, Japan

3. Department of Chemistry, Graduate School of Science, Kyoto University, Sakyo-ku, Kyoto 606-8502, Japan

4. Department of Chemistry and Molecular Materials Science, Graduate School of Science, Osaka City University, 3-3-138 Sugimoto, Sumiyoshi-ku, Osaka 558-8585, Japan

5. Molecular Photoscience Research Center, Kobe University, 1-1 Rokkodai-cho, Nada-ku, Kobe 657-8501, Japan

Funder

Ministry of Education, Culture, Sports, Science and Technology

Air Force Office of Scientific Research

Japan Society for the Promotion of Science

Cabinet Office, Government of Japan

Publisher

American Chemical Society (ACS)

Subject

General Materials Science,Physical and Theoretical Chemistry

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