Competition between Wolff Rearrangement and 1,2-Hydrogen Shift in β-Oxy-α-ketocarbenes: Electrostatic and Specific Solvent Effects
Author:
Affiliation:
1. Departamento de Química Física, Universidad de Málaga, Campus de Teatinos. 29071, Málaga, Spain, and Departamento de Química Física y Analítica, Universidad de Oviedo, Julián Clavería 33006, Oviedo, Spain
Publisher
American Chemical Society (ACS)
Subject
Materials Chemistry,Surfaces, Coatings and Films,Physical and Theoretical Chemistry
Link
https://pubs.acs.org/doi/pdf/10.1021/jp9909863
Reference33 articles.
1. The Wolff Rearrangement of ?-Diazo Carbonyl Compounds
2. β-Oxy-α-diazo carbonyl compounds. I. Photochemistry of chiral β-oxy-α-diazo methyl ketones. Stereoselective synthesis of chiral macrolide synthons.
3. β-oxy-α-diazo carbonyl compounds. II. conversion to chiral α-oxy-α′-diazo ketones and photochemical reaction
4. AM1 study of Wolff and 1,2-hydrogen shift rearrangements of β-oxy-α-Diazo carbonyl compounds
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