Formation of Intramolecular Three-Electron-Bonded 2σ/1σ* Radical Cations upon Reduction of Dialkylsulfinyl Sulfides by H-Atoms

Author:

Kishore Kamal1,Anklam Elke1,Aced Ahmed1,Asmus Klaus-Dieter1

Affiliation:

1. Applied Chemistry Division, Bhabha Atomic Research Centre, Mumbai 400 085, India; Commission for European Communities, Joint Research Centre Ispra, Environment Institute, I-21020 Ispra, Italy; Iris Technologies L.L.C., 3008 Oxford Rd., Lawrence, Kansas 66049; and Radiation Laboratory and Department of Chemistry and Biochemistry, University of Notre Dame, Notre Dame, Indiana 46556

Publisher

American Chemical Society (ACS)

Subject

Physical and Theoretical Chemistry

Reference41 articles.

1. Stabilization of oxidized sulfur centers in organic sulfides. Radical cations and odd-electron sulfur-sulfur bonds

2. Asmus, K.D. InSulfur-Centered Three-Electron Bonded Radical Species; Chatgilialoglu, C., Asmus, K.D., Eds.; Plenum Press:  New York, 1990; Vol. 197, p 155.

3. Asmus, K.D.; Bonifacic, M. InSulfur-Centered Reactive Intermediates asStudied by Radiation Chemical and Complementary Techniques; Alfassi, Z. B., Ed.; John Wiley & Sons Ltd.  New York, 1999; p 141.

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