Construction of Metal Butterflies on a Metallacarborane Scaffold. 1. Synthesis and Structures of Bimetallic Precursors
Author:
Affiliation:
1. Department of Chemistry & Biochemistry, Baylor University, Waco, Texas 76798-7348
Publisher
American Chemical Society (ACS)
Subject
Inorganic Chemistry,Organic Chemistry,Physical and Theoretical Chemistry
Link
https://pubs.acs.org/doi/pdf/10.1021/om060417z
Reference41 articles.
1. Metal complexes of monocarbon carboranes bearing C-amine or -amino substituents
2. Metal Complexes of Monocarbon Carboranes: A Neglected Area of Study?
3. Reactivity of the molybdenacarbaborane anion [2,2,2,2-(CO)4-closo-2,1-MoCB10H11]–: metal oxidation versus cage substitution†
4. Synthesis and reactivity of icosahedral molybdenum-monocarbaborane complexes containing one or two intramolecular amino bridgesThe new compounds described herein are based upon closo-1-carba-2-molybdenadodecaborane fragments, and all bear boron-bound exopolyhedral substituents. It should be noted that, although they contain chiral centres, species here occur as racemates. Substitued boron atoms at positions 3, 7, 11 or 6 could equally be labeled 6, 11, 7 and 3, respectively. In each case the former is used, in accordance with IUPAC convention.
5. The seventeen- and eighteen-electron metallacarbaboranes [1,1,1-(CO)3-2-Ph-closo-1,2-MnCB9H9]n? (n = 1, 2): a structurally characterized, redox-related pair
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