Synthesis of (+)-Bullatacin via the Highly Diastereoselective [3+2] Annulation Reaction of a Racemic Aldehyde and a Nonracemic Allylsilane
Author:
Affiliation:
1. Department of Chemistry, University of Michigan, Ann Arbor, Michigan 48109
Publisher
American Chemical Society (ACS)
Subject
Organic Chemistry,Physical and Theoretical Chemistry,Biochemistry
Link
https://pubs.acs.org/doi/pdf/10.1021/ol051719k
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3. Synthesis of (−)-bullatacin: The enantiomer of a potent, antitumor, 4-hydroxylated, Annonaceous acetogenin
4. Diastereoselective Reactions of Chiral Allyl and Allenyl Silanes with Activated C:X .pi.-Bonds
5. Diastereoselective additions of chiral (E)-crotylsilanes to .alpha.-alkoxy and .beta.-alkoxy aldehydes. A one-step, silicon-directed tetrahydrofuran synthesis
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