σ-Alkynyl Adsorption Enables Electrocatalytic Semihydrogenation of Terminal Alkynes with Easy-Reducible/Passivated Groups over Amorphous PdS<i><sub>x</sub></i> Nanocapsules-Reference-Cited by-同舟云学术

σ-Alkynyl Adsorption Enables Electrocatalytic Semihydrogenation of Terminal Alkynes with Easy-Reducible/Passivated Groups over Amorphous PdS_x Nanocapsules

Published:2022-10-05 Issue:42 Volume:144 Page:19456-19465
ISSN:0002-7863
Container-title:Journal of the American Chemical Society
language:en
Short-container-title:J. Am. Chem. Soc.

Author:

Li Huizhi¹,Gao Ying¹,Wu Yongmeng¹,Liu Cuibo¹²,Cheng Chuanqi³^ORCID,Chen Fanpeng¹,Shi Yanmei¹^ORCID,Zhang Bin¹²^ORCID

Affiliation:

1. Department of Chemistry, Institute of Molecular Plus, School of Science, Tianjin University, Tianjin 300072, China

2. Haihe Laboratory of Sustainable Chemical Transformations, Tianjin 300192, China

3. Institute of New Energy Materials, School of Materials Science and Engineering, Tianjin University, Tianjin 300072, China

Funder

National Natural Science Foundation of China

Publisher

American Chemical Society (ACS)

Subject

Colloid and Surface Chemistry,Biochemistry,General Chemistry,Catalysis

Link

https://pubs.acs.org/doi/pdf/10.1021/jacs.2c07742

Reference54 articles.

1. Are Alkyne Reductions Chemo-, Regio-, and Stereoselective Enough To Provide Pure (Z)-Olefins in Polyfunctionalized Bioactive Molecules?

2. Highly efficient ethylene production via electrocatalytic hydrogenation of acetylene under mild conditions

3. Iron-Catalyzed Regiodivergent Hydrostannation of Alkynes: Intermediacy of Fe(IV)–H versus Fe(II)–Vinylidene

4. Room-temperature electrochemical acetylene reduction to ethylene with high conversion and selectivity

5. Catalyst as colour indicator for endpoint detection to enable selective alkyne trans-hydrogenation with ethanol

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