Facile Generation of Lithiocarbyne Complexes: [M(≡CLi)(CO)2{HB(pzMe2)3}] (M = Mo, W; pz = Pyrazol-1-yl)

Author:

Cordiner Richard L.1,Hill Anthony F.1,Wagler Jörg1

Affiliation:

1. Research School of Chemistry, Institute of Advanced Studies, The Australian National University, Canberra, Australian Capital Territory 0200, Australia, and Institut für Anorganische Chemie, Technische Universität Bergakademie Freiberg, D-09596 Freiberg, Germany

Publisher

American Chemical Society (ACS)

Subject

Inorganic Chemistry,Organic Chemistry,Physical and Theoretical Chemistry

Reference25 articles.

1. Reactions of an Amphoteric Terminal Tungsten Methylidyne Complex

2. bJamison, G. M.; White, P. S.; Harris, D. L.; Templeton, J. L.InTransition Metal Carbyne Complexes;Kreissl, F. R., Ed.Kluwer Academic:Dordrecht, The Netherlands, 1992; Proceedings of the NATO Advanced Research Workshop on Transition Metal Carbyne Complexes, Wildbad Kreuth, Germany., p201.

3. Monomeric Group VI (M = molybdenum, tungsten) methylidyne complexes and their dimerization to nonclassical vinylidene-bridged Tp'(CO)2M(.mu.-CCH2)M(CO)2Tp' products

4. A terminal molybdenum carbide prepared by methylidyne deprotonation

5. Atomic Carbon as a Terminal Ligand:  Studies of a Carbidomolybdenum Anion Featuring Solid-State 13C NMR Data and Proton-Transfer Self-Exchange Kinetics

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