Total Syntheses of the Dihydrofuranonecarboxylate Natural Products Gregatin B and E: Gram-Scale Synthesis of (+)-Gregatin B and Unambiguous Assignment of the Stereostructure of (+)-Gregatin E
Author:
Affiliation:
1. Institut für Organische Chemie, Albert-Ludwigs-Universität, Albertstraße 21, 79104 Freiburg im Breisgau, Germany
Funder
Studienstiftung des Deutschen Volkes
Publisher
American Chemical Society (ACS)
Subject
Organic Chemistry,Physical and Theoretical Chemistry,Biochemistry
Link
https://pubs.acs.org/doi/pdf/10.1021/ol5032602
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3. Cadophora gregatawas originally namedCephalosporinum gregatum[Allington, W. B.; Chamberlain, D. W.Phytopathology 1948, 38, 793–802; cited according tohttp://www.indexfungorum.org/Names/NamesRecord.asp?RecordID=284846(15.07.14)]. It was first renamed toPhialophora gregata[Gams, W.Chephalosporinum-artige Schimmelpilze, 1971, ISBN:3437301179, p199; cited according tohttp://www.indexfungorum.org/Names/NamesRecord.asp?RecordID=319845(15.07.14)] and finally re-renamed toCadophora gregata(Harrington, T. C.; McNew, D. L.Mycotaxon 2003, 87, 141–151).
4. Vinylic carbanions in synthesis. Novel syntheses of iso-gregatin B, iso-aspertetronin A and related O-methyl tetronic acids
5. Synthesis of isoaspertetronin, isogregatin and related O-methyltetronic acids. Reassignment of 5-methoxyfuran-3(2H)-one structures to the aspertetronin group of natural products
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