Stoichiometric and Catalytic Conversion of 1-Adamantyl Azide to 1-Adamantyl Isocyanate by [Cr(CO)3Cp]2 and Reaction with Mo(CO)3(PiPr3)2 To Form Mo(κ2-iPr3P═NN═NAd)(CO)3(PiPr3)-Reference-Cited by-同舟云学术

Stoichiometric and Catalytic Conversion of 1-Adamantyl Azide to 1-Adamantyl Isocyanate by [Cr(CO)3Cp]2 and Reaction with Mo(CO)3(PiPr3)2 To Form Mo(κ2-iPr3P═NN═NAd)(CO)3(PiPr3)

Published:2009-05-18 Issue:13 Volume:28 Page:3587-3590
ISSN:0276-7333
Container-title:Organometallics
language:en
Short-container-title:Organometallics

Author:

Fortman George C.¹,Captain Burjor¹,Hoff Carl D.¹

Affiliation:

1. Chemistry Department, University of Miami, Coral Gables, Florida 33146

Publisher

American Chemical Society (ACS)

Subject

Inorganic Chemistry,Organic Chemistry,Physical and Theoretical Chemistry

Link

https://pubs.acs.org/doi/pdf/10.1021/om900004k

Reference18 articles.

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2. bPlatz, M. S.InReactive Intermediate Chemistry;Moss, R. A., Platz, M. S., Jones, M., Eds.John Wiley & Sons, Inc.:New York, 2005; p501.

3. Spectroscopic Detection and Theoretical Confirmation of the Role of Cr2(CO)5(C5R5)2 and ·Cr(CO)2(ketene)(C5R5) as Intermediates in Carbonylation of NNCHSiMe3 to OCCHSiMe3 by ·Cr(CO)3(C5R5) (R = H, CH3)

4. Kinetic and Thermodynamic Studies of the Reactivity of (Trimethylsilyl)diazomethane with HMo(CO)3(C5R5) (R = H, Me). Estimation of the Mo−N2CH2SiMe3 Bond Strength and Experimental Determination of the Enthalpy of Formation of (Trimethylsilyl)diazomethane

5. Thermodynamic and kinetic studies of stable low valent transition metal radical complexes

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