Evidence against Single-Electron Transfer in the Additions of Most Organomagnesium Reagents to Carbonyl Compounds
Author:
Affiliation:
1. Department of Chemistry, New York University, 100 Washington Square East, New York, New York 10003, United States
Funder
American Chemical Society Petroleum Research Fund
National Institute of General Medical Sciences
Publisher
American Chemical Society (ACS)
Subject
Organic Chemistry
Link
https://pubs.acs.org/doi/pdf/10.1021/acs.joc.0c00481
Reference48 articles.
1. The Grignard Reaction – Unraveling a Chemical Puzzle
2. Mechanistic Insight into Additions of Allylic Grignard Reagents to Carbonyl Compounds
3. Reactions of Allylmagnesium Halides with Carbonyl Compounds: Reactivity, Structure, and Mechanism
4. Evidence that Additions of Grignard Reagents to Aliphatic Aldehydes Do Not Involve Single-Electron-Transfer Processes
5. Ultrafast Grignard addition reactions in the presence of water
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