Rotational Behavior of <i>N</i>-(5-Substituted-pyrimidin-2-yl)anilines: Relayed Electronic Effect in Two N–Ar Bond Rotations-Reference-Cited by-同舟云学术

Rotational Behavior of N-(5-Substituted-pyrimidin-2-yl)anilines: Relayed Electronic Effect in Two N–Ar Bond Rotations

Published:2022-06-03 Issue:12 Volume:87 Page:8118-8125
ISSN:0022-3263
Container-title:The Journal of Organic Chemistry
language:en
Short-container-title:J. Org. Chem.

Author:

Homma Daiki¹,Taketani Shuhei¹,Shirai Takeshi¹,Caytan Elsa²^ORCID,Roussel Christian³,Elguero José⁴^ORCID,Alkorta Ibon⁴^ORCID,Kitagawa Osamu¹^ORCID

Affiliation:

1. Department of Applied Chemistry (Japanese Association of Bio-intelligence for Well-being), Shibaura Institute of Technology, 3-7-5 Toyosu, Kohto-ku, Tokyo 135-8548, Japan

2. Univ Rennes, CNRS, ISCR − UMR 6226, F-35000 Rennes, France

3. Aix Marseille Université, Centrale Marseille, CNRS, iSm2 UMR 7313, 13397 Cedex 20 Marseille, France

4. Instituto de Química Médica, CSIC, Juan de la Cierva, 3, E-28006 Madrid, Spain

Funder

Japan Society for the Promotion of Science

Publisher

American Chemical Society (ACS)

Subject

Organic Chemistry

Link

https://pubs.acs.org/doi/pdf/10.1021/acs.joc.2c00845

Reference34 articles.

1. Axially Chiral Binaphthyl Surrogates with an Inner N−H−N Hydrogen Bond

2. Heavily Substituted Atropisomeric Diarylamines by Unactivated Smiles Rearrangement of N ‐Aryl Anthranilamides

3. Catalytic Atroposelective Synthesis of N-Aryl Quinoid Compounds

4. Atropisomerism in Diarylamines: Structural Requirements and Mechanisms of Conformational Interconversion

5. Approaches toward Atropisomerically Stable and Conformationally Pure Diarylamines

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