Polar Effects in Hydrogen Atom Transfer Reactions from a Proton-Coupled Electron Transfer (PCET) Perspective: Abstractions from Toluenes
Author:
Affiliation:
1. Department of Chemistry, Yale University, New Haven, Connecticut 06520, United States
Funder
Yale University
Directorate for Education and Human Resources
National Institute of General Medical Sciences
Publisher
American Chemical Society (ACS)
Subject
Organic Chemistry
Link
https://pubs.acs.org/doi/pdf/10.1021/acs.joc.3c01748
Reference92 articles.
1. The interplay of polar effects in controlling the selectivity of radical reactions
2. Polarity-reversal catalysis of hydrogen-atom abstraction reactions: concepts and applications in organic chemistry
3. Which Factors Determine the Reactivity and Regioselectivity of Free Radical Substitution and Addition Reactions?
4. Reactivity and Selectivity Patterns in Hydrogen Atom Transfer from Amino Acid C–H Bonds to the Cumyloxyl Radical: Polar Effects as a Rationale for the Preferential Reaction at Proline Residues
5. Peculiar Stability of Amino Acids and Peptides from a Radical Perspective
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