Preparation and Crystal Structure of Two Bicyclo[1.1.0]butan-2-ones: A Hybrid Oxyallyl−Cyclopropanone Motif
Author:
Affiliation:
1. Department of Chemistry, University of Calgary, 2500 University Drive, Calgary, Alberta, T2N 1N4 Canada
Publisher
American Chemical Society (ACS)
Subject
Colloid and Surface Chemistry,Biochemistry,General Chemistry,Catalysis
Link
https://pubs.acs.org/doi/pdf/10.1021/ja043646q
Reference14 articles.
1. For example, (a) the Favorskii rearrangement: Chenier, P. J.J.Chem.Educ.1978,55, 286−291. (b) Alleneoxide rearrangements: Hess, B. A., Jr.; Eckart, U.; Fabian, J.J. Am. Chem. Soc.1998,120, 12310−12315. (c) Photochemistry of dienones: Schaffner, K.; Demuth, M. M. InRearrangements in Ground and Excited States; de Mayo, P., Ed.; Academic Press: New York, 1980; Vol. 3, pp 281−319. (d) [3 + 4] Cycloaddition reactions: Turro, N. J.Acc. Chem. Res.1969,2, 25−32.
2. Novel photoreactions of benzhydrylidenequadricyclane and quadricyclanone: a new route to trimethylenemethane and oxyallyl derivatives
3. Ring Opening of Bicyclo[n.1.0]alkanones to 2-Cycloalkanone-1,3-diyls. Why Does Oxyallyl Diradical Formation Require Less Energy from Bicyclo[3.1.0]hexan-6-ones than from Bicyclo[1.1.0]butan-2-ones?
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