Preparation and Crystal Structure of Two Bicyclo[1.1.0]butan-2-ones:  A Hybrid Oxyallyl−Cyclopropanone Motif

Author:

Bhargava Surbhi1,Hou Jianjun1,Parvez Masood1,Sorensen Ted S.1

Affiliation:

1. Department of Chemistry, University of Calgary, 2500 University Drive, Calgary, Alberta, T2N 1N4 Canada

Publisher

American Chemical Society (ACS)

Subject

Colloid and Surface Chemistry,Biochemistry,General Chemistry,Catalysis

Reference14 articles.

1. For example, (a) the Favorskii rearrangement:  Chenier, P. J.J.Chem.Educ.1978,55, 286−291. (b) Alleneoxide rearrangements:  Hess, B. A., Jr.; Eckart, U.; Fabian, J.J. Am. Chem. Soc.1998,120, 12310−12315. (c) Photochemistry of dienones:  Schaffner, K.; Demuth, M. M. InRearrangements in Ground and Excited States; de Mayo, P., Ed.; Academic Press:  New York, 1980; Vol. 3, pp 281−319. (d) [3 + 4] Cycloaddition reactions:  Turro, N. J.Acc. Chem. Res.1969,2, 25−32.

2. Novel photoreactions of benzhydrylidenequadricyclane and quadricyclanone: a new route to trimethylenemethane and oxyallyl derivatives

3. Ring Opening of Bicyclo[n.1.0]alkanones to 2-Cycloalkanone-1,3-diyls. Why Does Oxyallyl Diradical Formation Require Less Energy from Bicyclo[3.1.0]hexan-6-ones than from Bicyclo[1.1.0]butan-2-ones?

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