Reactivity of [Os3(μ-H)2(CO)10] with N-Heterocyclic Carbenes: A Combined Experimental and DFT Computational Study
Author:
Affiliation:
1. Departamento de Química Orgánica e Inorgánica-IUQOEM, Universidad de Oviedo-CSIC, E-33071 Oviedo, Spain
2. Departamento de Química Física y Analítica, Universidad de Oviedo, E-33071 Oviedo, Spain
Publisher
American Chemical Society (ACS)
Subject
Inorganic Chemistry,Organic Chemistry,Physical and Theoretical Chemistry
Link
https://pubs.acs.org/doi/pdf/10.1021/om100679a
Reference62 articles.
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2. Reactivity of N-Heterocyclic Carbenes with [Ru3(CO)12] and [Os3(CO)12]. Influence of Ligand Volume and Electronic Effects
3. Easy activation of two C–H bonds of an N-heterocyclic carbene N-methyl group
4. Activation of two C–H bonds of NHC N-methyl groups on triosmium and triruthenium carbonyl clusters
5. Double C−H Bond Activation of an NHC N-Methyl Group on Triruthenium and Triosmium Carbonyl Clusters: A DFT Mechanistic Study
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