Activation of the C−H Bond by Electrophilic Attack: Theoretical Study of the Reaction Mechanism of the Aerobic Oxidation of Alcohols to Aldehydes by the Cu(bipy)2+/2,2,6,6-Tetramethylpiperidinyl-1-oxy Cocatalyst System-Reference-Cited by-同舟云学术

Activation of the C−H Bond by Electrophilic Attack: Theoretical Study of the Reaction Mechanism of the Aerobic Oxidation of Alcohols to Aldehydes by the Cu(bipy)2+/2,2,6,6-Tetramethylpiperidinyl-1-oxy Cocatalyst System

Published:2009-11-25 Issue:24 Volume:48 Page:11909-11920
ISSN:0020-1669
Container-title:Inorganic Chemistry
language:en
Short-container-title:Inorg. Chem.

Author:

Michel Carine¹,Belanzoni Paola²,Gamez Patrick³,Reedijk Jan³,Baerends Evert Jan¹⁴

Affiliation:

1. Theoretical Chemistry, VU University Amsterdam, De Boelelaan 1083, 1081 HV Amsterdam, The Netherlands

2. Dipartimento di Chimica, Università di Perugia, I-06123 Perugia, Italy

3. Leiden Institute of Chemistry, Leiden University, P.O. Box 9502, NL-2300 RA Leiden, The Netherlands

4. Department of Chemistry, Pohang University of Science and Technology, Pohang 790-784, South-Korea

Publisher

American Chemical Society (ACS)

Subject

Inorganic Chemistry,Physical and Theoretical Chemistry

Link

https://pubs.acs.org/doi/pdf/10.1021/ic902155m

Reference37 articles.

1. Oxidation of alcohols to aldehydes with oxygen and cupric ion, mediated by nitrosonium ion

2. Mechanism of the oxidation of alcohols by 2,2,6,6-tetramethylpiperidine nitrosonium cation

3. The TEMPO/Copper Catalyzed Oxidation of Primary Alcohols to Aldehydes Using Oxygen as Stoichiometric Oxidant

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