Highly Enantioselective Hydroformylation of Olefins Catalyzed by Rhodium(I) Complexes of New Chiral Phosphine−Phosphite Ligands

Author:

Nozaki Kyoko1,Sakai Nozomu1,Nanno Tetsuo1,Higashijima Takanori1,Mano Satoshi1,Horiuchi Toshihide1,Takaya Hidemasa1

Affiliation:

1. Contribution from the Department of Material Chemistry, Graduate School of Engineering, Kyoto University, Sakyo-ku, Kyoto 606-01, Japan

Publisher

American Chemical Society (ACS)

Subject

Colloid and Surface Chemistry,Biochemistry,General Chemistry,Catalysis

Reference47 articles.

1. Platinum-catalyzed enantioselective hydroformylation with (R,R)-[bicyclo[2.2.2]octane-2,3-diylbis(methylene)]bis(5H-benzo[b]phosphindole) and related chiral ligands

2. Recent examples with Rh(I)−achiral phosphite complexes:  (a) van Leeuwen, P. W. N. M.; Roobeek, C. F. (Shell). Eur. Pat. Appl. EP 54986, 1982. (b) van Leeuwen, P. W. N. M.; Roobeek, C. F.J. Organomet. Chem.1983,258, 343. (c) Billig, E.; Abatjoglou, A. G.; Bryant, D. R. (Union Carbide). U.S. Pat. US 4769498, 1988. (d) Cuny, G. D.; Buchwald, S. L.J.Am. Chem. Soc.1993,115, 2066. (e) van Rooy, A.; Orij, E. N.; Kamer, P. C. J.; van Leeuwen, P. W. N. M.Organometallics1995,14, 34.

3. Practical syntheses of chelating bis(dioxaphospholane) ligands through chlorodioxaphospholane intermediates and demonstration of catalytic competence of bis(phosphite)rhodium cation

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