Competition between SN2 and Single Electron Transfer Reactions as a Function of Steric Hindrance Illustrated by the Model System AlkylCl + NO--Reference-Cited by-同舟云学术

Competition between SN2 and Single Electron Transfer Reactions as a Function of Steric Hindrance Illustrated by the Model System AlkylCl + NO-

Published:2000-02-26 Issue:10 Volume:122 Page:2329-2338
ISSN:0002-7863
Container-title:Journal of the American Chemical Society
language:en
Short-container-title:J. Am. Chem. Soc.

Author:

Costentin Cyrille¹,Savéant Jean-Michel¹

Affiliation:

1. Contribution from the Laboratoire d'Electrochimie Moléculaire, Unité Mixte de Recherche Université, CNRS No 7591, Université de Paris 7-Denis Diderot, Case Courrier 7107, 2 place Jussieu, 75251 Paris Cedex 05, France

Publisher

American Chemical Society (ACS)

Subject

Colloid and Surface Chemistry,Biochemistry,General Chemistry,Catalysis

Link

https://pubs.acs.org/doi/pdf/10.1021/ja993467m

Reference48 articles.

1. Electron transfer, naphthalene radical anion, and alkyl halides

2. Reactions of aromatic radical anions. 12. Kinetic studies of the reaction of radical anions of varying reduction potential with n-hexyl bromides, iodides, and chlorides

3. Dissociative electron transfer. Homogeneous and heterogeneous reductive cleavage of the carbon-halogen bond in simple aliphatic halides

4. Single Electron Transfer as Rate-Determining Step in an Aliphatic Nucleophilic Substitution.

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