Steric Protection of the Selenium Atom of the Episelenonium Ion Intermediate To Prevent both the Racemization of the Chiral Carbon and the Selenophilic Attack of Carbon Nucleophiles-Reference-Cited by-同舟云学术

Steric Protection of the Selenium Atom of the Episelenonium Ion Intermediate To Prevent both the Racemization of the Chiral Carbon and the Selenophilic Attack of Carbon Nucleophiles

Published:1996-01-01 Issue:11 Volume:118 Page:2756-2757
ISSN:0002-7863
Container-title:Journal of the American Chemical Society
language:en
Short-container-title:J. Am. Chem. Soc.

Author:

Toshimitsu Akio¹,Nakano Katsuhiro¹,Mukai Takao¹,Tamao Kohei¹

Affiliation:

1. Institute for Chemical Research, Kyoto University Uji, Kyoto 611, Japan

Publisher

American Chemical Society (ACS)

Subject

Colloid and Surface Chemistry,Biochemistry,General Chemistry,Catalysis

Link

https://pubs.acs.org/doi/pdf/10.1021/ja9538445

Reference6 articles.

1. Asymmetric Reaction of Arylalkenes with Diselenides

2. The stereochemistry of a substitution reaction via an episelenonium ion: retention by a 2-pyridylseleno group versus scrambling by a phenylseleno group

3. Alkene carbosulphenylation and carboselenylation: The use of allyltrimethylsilane and o-silylated enolates.

4. Amidoselenation of olefins via hydroxyselenation: reactions using nitriles in reagent quantity and the synthesis of β-(acrylamido)alkyl phenyl selenides

5. Notiz über die Darstellung tert.‐butylierter Thiophenole, Diphenyldisulfide und Thianthrene

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