Mechanism of Dimethylallyltryptophan Synthase: Evidence for a Dimethylallyl Cation Intermediate in an Aromatic Prenyltransferase Reaction
Author:
Affiliation:
1. Department of Chemistry, University of British Columbia, 2036 Main Mall, Vancouver, BC V6T-1Z1, Canada
Publisher
American Chemical Society (ACS)
Subject
Colloid and Surface Chemistry,Biochemistry,General Chemistry,Catalysis
Link
https://pubs.acs.org/doi/pdf/10.1021/ja906485u
Reference31 articles.
1. Chemoenzymatic Synthesis of Prenylated Indole Derivatives by Using a 4-Dimethylallyltryptophan Synthase fromAspergillus fumigatus
2. Dimethylallyltryptophan synthase. An enzyme-catalyzed electrophilic aromatic substitution
3. Stereochemistry of the isoprenylation of tryptophan catalyzed by 4-(.gamma.,.gamma.-dimethylallyl)tryptophan synthase from Claviceps, the first pathway-specific enzyme in ergot alkaloid biosynthesis
4. Molecular Analysis of a 4-Dimethylallyltryptophan Synthase from Malbranchea aurantiaca
5. Overproduction, purification and characterization of FgaPT2, a dimethylallyltryptophan synthase from Aspergillus fumigatus
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