Unusual Temperature Dependence in the cis/trans-Oxetane Formation Discloses Competitive Syn versus Anti Attack for the Paternò−Büchi Reaction of Triplet-Excited Ketones with cis- and trans-Cylooctenes. Conformational Control of Diastereoselectivity in the Cyclization and Cleavage of Preoxetane Diradicals

Author:

Adam Waldemar1,Stegmann Veit R.1

Affiliation:

1. Contribution from the Institut für Organische Chemie, Universität Würzburg, Am Hubland, D-97074 Würzburg, Germany

Publisher

American Chemical Society (ACS)

Subject

Colloid and Surface Chemistry,Biochemistry,General Chemistry,Catalysis

Reference39 articles.

1. Light-catalyzed Organic Reactions. I. The Reaction of Carbonyl Compounds with 2-Methyl-2-butene in the Presence of Ultraviolet Light

2. (a) Griesbeck, A. G.; Fiege, M. InMolecular and SupramolecularPhotochemistry; Ramamurthy, V., Schanze, K. S., Eds.; Marcel Dekker:  New York, 2000; Vol. 6, p 33.

3. (b) Fleming, S. A.; Bradford, C. L.; Gao, J. J. InMolecular and Supramolecular Photochemistry; Ramamurthy, V., Schanze, K. S., Eds.; Marcel Dekker:  New York, 1997; Vol. 1, p 187.

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