Regioselective Protonation of the η4-Anthracene Ligand in [Mn(η4-C14H10)(CO)3]- To Give an η5-Anthracenyl Complex [Mn(η5-C14H11)(CO)3] That Undergoes a Low-Energy 1,4-Hydride Exchange Reaction-Reference-Cited by-同舟云学术

Regioselective Protonation of the η4-Anthracene Ligand in [Mn(η4-C14H10)(CO)3]- To Give an η5-Anthracenyl Complex [Mn(η5-C14H11)(CO)3] That Undergoes a Low-Energy 1,4-Hydride Exchange Reaction

Published:2000-01-26 Issue:4 Volume:19 Page:661-671
ISSN:0276-7333
Container-title:Organometallics
language:en
Short-container-title:Organometallics

Author:

Veauthier Jacqueline M.¹,Chow Albert¹,Fraenkel Gideon¹,Geib Steven J.¹,Cooper N. John¹

Affiliation:

1. Departments of Chemistry, University of Pittsburgh, Pittsburgh, Pennsylvania 15260, and Ohio State University, Columbus, Ohio 43210

Publisher

American Chemical Society (ACS)

Subject

Inorganic Chemistry,Organic Chemistry,Physical and Theoretical Chemistry

Link

https://pubs.acs.org/doi/pdf/10.1021/om990735g

Reference49 articles.

1. Electrophilic activation of benzene in [Cr(.eta.4-C6H6)(CO)3]2-

2. Metal-mediated addition of carbon dioxide to the activated benzene in [Cr(.eta.4-C6H6)(CO)3]2-

3. Facile exchange of naphthalene for .eta.4-benzene in [Cr(.eta.4-C6H6)(CO)3]2-

4. Reductive activation of the coordinated benzene in manganese complex [Mn(.eta.6-C6H6)(CO)3]+: synthesis and characterization of the .eta.4-naphthalene complex PPN[Mn(.eta.4-C10H8)(CO)3]

5. [2 + 2]cyclodimerization of ligated benzene following reductive activation of manganese complex [Mn(.eta.6-C6H6)(CO)3]+ to give [{Mn(CO)3}2{[.mu.(.eta.4-C6H6-.eta.4-C6H6)}]2-

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