A Computational Study of Reductive Elimination Reactions to Form C−H Bonds from Pt(II) and Pt(IV) Centers. Why Does Ligand Loss Precede Reductive Elimination from Six-Coordinate but Not Four-Coordinate Platinum?-Reference-Cited by-同舟云学术

A Computational Study of Reductive Elimination Reactions to Form C−H Bonds from Pt(II) and Pt(IV) Centers. Why Does Ligand Loss Precede Reductive Elimination from Six-Coordinate but Not Four-Coordinate Platinum?

Published:2000-02-01 Issue:7 Volume:122 Page:1456-1465
ISSN:0002-7863
Container-title:Journal of the American Chemical Society
language:en
Short-container-title:J. Am. Chem. Soc.

Author:

Bartlett Kevin L.¹,Goldberg Karen I.¹,Borden Weston Thatcher¹

Affiliation:

1. Contribution from the Department of Chemistry, Box 351700, University of Washington, Seattle, Washington 98195-1700

Publisher

American Chemical Society (ACS)

Subject

Colloid and Surface Chemistry,Biochemistry,General Chemistry,Catalysis

Link

https://pubs.acs.org/doi/pdf/10.1021/ja9915706

Reference66 articles.

1. Theoretical Study of Oxidative Addition and Reductive Elimination of 14-Electron d10 ML2 Complexes: A ML2 + CH4 (M = Pd, Pt; L = CO, PH3, L2 = PH‘2CH2CH2PH2) Case Study

2. Theoretical studies of oxidative addition and reductive elimination. 3. Carbon-hydrogen and carbon-carbon reductive coupling from palladium and platinum bis(phosphine) complexes

3. Reaction mechanisms of oxidative addition hydrogen + diphosphineplatinum(0) .fwdarw. dihydridodiphosphineplatinum(II) and reductive elimination hydridomethyldiphosphineplatinum(II) .fwdarw. methane + diphosphineplatinum(0). Ab initio MO study

4. Reductive elimination of HH, HCH3, and CH3CH3 from bis(phosphine)platinum(II), -palladium(II), and -nickel(II) complexes: a theoretical study using the SCF-X.alpha.-SW method

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