Synthesis and Characterization of (Et4N)4[MoS4Cu10Cl12]: A Polynuclear Molybdenum−Copper Cluster Containing a Central Tetrahedral MoS4 Encapsulated by Octahedral Cu6 and Tetrahedral Cu4 Arrays
Author:
Affiliation:
1. State Key Laboratory of Structural Chemistry, Fujian Institute of Research on the Structure of Matter, Chinese Academy of Sciences, Fujian, Fuzhou, 350002, China
Publisher
American Chemical Society (ACS)
Subject
Inorganic Chemistry,Physical and Theoretical Chemistry
Link
https://pubs.acs.org/doi/pdf/10.1021/ic9410304
Reference18 articles.
1. Preparation, crystal structure, and spectroscopic studies of [NPrn4]2[(PhS)CuS2MoS2] and [NPrn4]2[(PhS)CuS2MoS2Cu(SPh)], containing benzenethiolatocopper(I)–tetrathiomolybdate(VI) complex anions
2. (Ph4P)2[CuCN(MoS4)] and(Me4N)2(CuCN)2MoS4: Thiomolybdate Ligands on the Cu Atoms of a CuCN Molecule and azigzag-CuCN Chain
3. The preparation of different types of polynuclear transition metal sulfur compounds by thiometallates, including cubane-like ones. Crystal structures of {Cu3WS3Cl}(PPh3)3S, {Cu3WS3Cl}(PPh3)3O, {Cu3MoS3Cl}(PPh3)3S, {Cu3MoS3Cl}(PPh33O, (PPh3)3Cu2WS4·0.8CH2Cl2 and (PPh3)3Ag2MoS4·0.8CH2Cl2
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