Palladium-Catalyzed Defluorinative Alkylation of <i>gem</i>-Difluoroalkenes with Cyclopropanols: Stereoselective Synthesis of γ-Fluorinated γ,δ-Unsaturated Ketones-Reference-Cited by-同舟云学术

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Palladium-Catalyzed Defluorinative Alkylation of gem-Difluoroalkenes with Cyclopropanols: Stereoselective Synthesis of γ-Fluorinated γ,δ-Unsaturated Ketones

Published:2024-04-25 Issue:17 Volume:26 Page:3591-3596
ISSN:1523-7060
Container-title:Organic Letters
language:en
Short-container-title:Org. Lett.

Author:

Kong Lingyu¹,Ti Wenqing²,Lin Aijun²^ORCID,Yao Hequan¹,Huang Yue³,Li Xuanyi²^ORCID

Affiliation:

1. Department of Medicinal Chemistry, China Pharmaceutical University, 639 Longmian Avenue, Nanjing, Jiangsu 210009, China

2. State Key Laboratory of Natural Medicines (SKLNM) and Department of Medicinal Chemistry, School of Pharmacy, China Pharmaceutical University, 24 Tongjiaxiang, Nanjing, Jiangsu 210009, China

3. Department of Chemistry, School of Science, China Pharmaceutical University, Nanjing, Jiangsu 211098, China

Funder

State Key Laboratory of Natural Medicines

National Natural Science Foundation of China

Publisher

American Chemical Society (ACS)

Link

https://pubs.acs.org/doi/pdf/10.1021/acs.orglett.4c01045

Reference53 articles.

1. C−F and C−H Bond Activation of Fluorobenzenes and Fluoropyridines at Transition Metal Centers: How Fluorine Tips the Scales

2. Functionalization of Fluorinated Molecules by Transition-Metal-Mediated C–F Bond Activation To Access Fluorinated Building Blocks

3. Transition-Metal-Mediated and -Catalyzed C−F Bond Activation by Fluorine Elimination

4. Recent Advances in Transition‐metal‐catalyzed C−C Bond Formation via C( sp 2 )−F Bond Cleavage

5. Metal-catalysed C–Het (F, O, S, N) and C–C bond arylation

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