Total Synthesis and Structural Revision of the 6,11-Epoxyisodaucane Natural Sesquiterpene Using an Anionic 8π Electrocyclic Reaction
Author:
Affiliation:
1. Graduate School of Chemical Sciences and Engineering, Hokkaido University, Sapporo 060-0810, Japan
2. Department of Chemistry, Faculty of Science, Hokkaido University, Sapporo 060-0810, Japan
Funder
Hokkaido University
Japan Society for the Promotion of Science
Publisher
American Chemical Society (ACS)
Subject
Organic Chemistry,Physical and Theoretical Chemistry,Biochemistry
Link
https://pubs.acs.org/doi/pdf/10.1021/acs.orglett.2c03068
Reference46 articles.
1. Recent Advances on the Application of Electrocyclic Reactions in Complex Natural Product Synthesis
2. Biosynthetic and Biomimetic Electrocyclizations
3. Stereoselective Synthesis of (±)-Cephanolide B
4. Divergent total syntheses of pseudoberberine and nitidine through C H vinylation and switchable 6π electrocyclizations
5. Total Synthesis of Calothrixin B via an Intramolecular Baylis‐Hillman Cyclization/6π Electrocyclization/Dehydro‐aromatization Sequence and a Specific Oxidative Quinone Formation
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