Spontaneous, Millisecond Formation of a Twisted Amide from the Amino Acid, and the Crystal Structure of a Tetrahedral Intermediate-Reference-Cited by-同舟云学术

Spontaneous, Millisecond Formation of a Twisted Amide from the Amino Acid, and the Crystal Structure of a Tetrahedral Intermediate

Published:1998-07-01 Issue:28 Volume:120 Page:7101-7102
ISSN:0002-7863
Container-title:Journal of the American Chemical Society
language:en
Short-container-title:J. Am. Chem. Soc.

Author:

Kirby Anthony J.¹,Komarov Igor V.¹,Feeder Neil¹

Affiliation:

1. University Chemical Laboratory Cambridge University Cambridge CB2 1EW, UK

Publisher

American Chemical Society (ACS)

Subject

Colloid and Surface Chemistry,Biochemistry,General Chemistry,Catalysis

Link

https://pubs.acs.org/doi/pdf/10.1021/ja980700s

Reference8 articles.

1. The Most Twisted Amide: Structure and Reactions

2. For3: colorless crystal, monoclinic, space groupP21/n,a= 7.800(7) Å,b= 13.441(8) Å,c= 12.494(8) Å, β = 100.00(6)°,V= 1290(2) Å3,Z= 4,R= 0.08, goodness of fit onF21.320. Crystallographic data (excluding structure factors) have been deposited with the Cambridge Crystallographic Data Centre (CCDC Registry no. 101155). Copies of the data can be obtained free of charge on application to The Director, CCDC, 12, Union Road, Cambridge CB2 1EZ, UK (GFax: int. code + (1223) 336-033).

3. The mechanism of the aminolysis of methyl formate

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