Interplay between the Directing Group and Multifunctional Acetate Ligand in Pd-Catalyzed <i>anti</i>-Acetoxylation of Unsymmetrical Dialkyl-Substituted Alkynes-Reference-Cited by-同舟云学术

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Interplay between the Directing Group and Multifunctional Acetate Ligand in Pd-Catalyzed anti-Acetoxylation of Unsymmetrical Dialkyl-Substituted Alkynes

Published:2022-05-19 Issue:11 Volume:12 Page:6596-6605
ISSN:2155-5435
Container-title:ACS Catalysis
language:en
Short-container-title:ACS Catal.

Author:

Corpas Javier¹^ORCID,Arpa Enrique M.²,Lapierre Romain¹,Corral Inés³⁴^ORCID,Mauleón Pablo¹⁴^ORCID,Arrayás Ramón Gómez¹⁴^ORCID,Carretero Juan C.¹⁴^ORCID

Affiliation:

1. Departamento de Química Orgánica, Facultad de Ciencias, Universidad Autónoma de Madrid (UAM), 28049 Madrid, Spain

2. Division of Theoretical Chemistry, IFM, Linköping University, 581 83 Linköping, Sweden

3. Departamento de Química, Facultad de Ciencias, UAM, Cantoblanco, 28049 Madrid, Spain

4. Institute for Advanced Research in Chemical Sciences (IAdChem), UAM, 28049 Madrid, Spain

Funder

Ministerio de Ciencia e Innovaci?n

European Regional Development Fund

Ministerio de Econom?a y Competitividad

Ministerio de Educaci?n, Cultura y Deporte

Publisher

American Chemical Society (ACS)

Subject

Catalysis,General Chemistry

Link

https://pubs.acs.org/doi/pdf/10.1021/acscatal.2c00710

Reference74 articles.

1. Multifunctional ligands in transition metal catalysis

2. On the Mechanism of Palladium(0) Catalyzed, Copper(I) Carboxylate Mediated Thioorganic−Boronic Acid Desulfitative Coupling. A Noninnocent Role for the Carboxylate Ligand

3. Carboxylate-Assisted Transition-Metal-Catalyzed C−H Bond Functionalizations: Mechanism and Scope

4. Proton-Abstraction Mechanism in the Palladium-Catalyzed Intramolecular Arylation: Substituent Effects

5. The continuum of carbon–hydrogen (C–H) activation mechanisms and terminology

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