Affiliation:
1. Department of Chemistry and Chemical Biology Harvard University Cambridge, Massachusetts 02138
Publisher
American Chemical Society (ACS)
Subject
Colloid and Surface Chemistry,Biochemistry,General Chemistry,Catalysis
Reference5 articles.
1. Two-Metal Ion Catalysis in Enzymatic Acyl- and Phosphoryl-Transfer Reactions
2. Dinuclear copper(II) complex that hydrolyzes RNA
3. Highly Enantioselective Ring Opening of Epoxides Catalyzed by (salen)Cr(III) Complexes
4. On the Mechanism of Asymmetric Nucleophilic Ring-Opening of Epoxides Catalyzed by (Salen)CrIII Complexes
5. Kinetic experiments analogous to those described for4a−g(Figure 3) indicated that, at the concentration studied ([2] = 1 × 10-3M), complex2catalyzed the ARO primarily through a first-order pathway. At higher [2], enantioselectivities in the ARO improved as a result of participation of a pathway that is second order in the dimer. For example, with [2] = 2 × 10-2M, the ARO product was obtained in 86% ee.
Cited by
372 articles.
订阅此论文施引文献
订阅此论文施引文献,注册后可以免费订阅5篇论文的施引文献,订阅后可以查看论文全部施引文献