The Redox Chemistry of [Co6C(CO)15]2–: A Synthetic Route to New Co-Carbide Carbonyl Clusters
Author:
Affiliation:
1. Dipartimento di Chimica Industriale “Toso Montanari”, Università di Bologna, Viale Risorgimento 4 - 40136 Bologna, Italy
2. Area della Ricerca, ICCOM-CNR UOS Pisa, Via G. Moruzzi 1, 56124 Pisa, Italy
Publisher
American Chemical Society (ACS)
Subject
Inorganic Chemistry,Physical and Theoretical Chemistry
Link
https://pubs.acs.org/doi/pdf/10.1021/ic500161e
Reference71 articles.
1. New arrangements of transition metal atoms in carbido-carbonyl clusters of rhodium and cobalt
2. New carbide clusters in the cobalt subgroup. Part 13. Synthesis and chemical characterization of the anions [Co6C(CO)14]–, [Co6C(CO)15]2–, and [Co8C(CO)18]2–, and crystal structure of µ6-carbido-ennea-µ-carbonyl-hexacarbonyl-polyhedro-hexacobaltate(2–) as its benzyltrimethylammonium salt; a comparison with isostructural species
3. New carbide clusters in the cobalt subgroup. Part 16. Preparation and structural characterization of µ6-carbido-penta-µ-carbonyl-octacarbonyl-octahedro-hexacobaltate(2–) as its tetraethylammonium salt
4. Stabilization of carbonyl clusters by a carbide atom. Synthesis and characterization of carbonoctadecacarbonyloctacobaltate(2-) and of paramagnetic carbontetradecacarbonylhexacobaltate(1-) anions
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