An X-ray analysis of the structure of chrysene

Author:

Abstract

Chrysene crystallizes in the monoclinic system. By means of rotation, oscillation, and moving film photographs the following crystal data have been obtained:— a = 8·34 A, b = 6·18 A, c = 25·0 A, β = 115·8°. All the planes ( hkl ) are halved when h + k + l is odd and in addition all the ( h 0 l ) planes are halved. There are two space groups available, C 6 2 h (I2/ c ) and C 4 s (I c ). In what follows it will be shown that the former space group is the more probable. The measured density is 1·27 (at room temperature) giving 4 molecules of C 18 H 12 per unit cell. Molecular volume = 290 (A) 3 .

Publisher

The Royal Society

Subject

General Medicine

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